SYNTHESIS OF A CROWN-ETHER FUNCTIONALIZED PHOSPHINE AND ITS NICKEL(II), PALLADIUM(II) AND PLATINUM(II) COMPLEXES


SERINDAG O.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, vol.25, no.2, pp.327-335, 1995 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 25 Issue: 2
  • Publication Date: 1995
  • Doi Number: 10.1080/15533179508218223
  • Title of Journal : SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Page Numbers: pp.327-335

Abstract

Treatment of 4'-aminobenzo-15-crown-5 (1) (Figure 1) with diphenylphosphine in the presence of formaldehyde or with the phosphonium salt [Ph(2)P(CH2OH)(2)]Cl in the presence of triethylamine gives a novel aminomethylphosphine (2). Nickel(II), palladium(II) and platinum(II) complexes of (2) have been synthesized and characterized by means of their P-31 and H-1 NMR and mass spectra and microanalytical data.