SYNTHESIS OF A CROWN-ETHER FUNCTIONALIZED PHOSPHINE AND ITS NICKEL(II), PALLADIUM(II) AND PLATINUM(II) COMPLEXES

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Atıf İçin Kopyala

SERINDAG O.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.25, sa.2, ss.327-335, 1995 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 25 Sayı: 2
• Basım Tarihi: 1995
• Doi Numarası: 10.1080/15533179508218223
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.327-335
• Çukurova Üniversitesi Adresli: Hayır

Özet

Treatment of 4'-aminobenzo-15-crown-5 (1) (Figure 1) with diphenylphosphine in the presence of formaldehyde or with the phosphonium salt [Ph(2)P(CH2OH)(2)]Cl in the presence of triethylamine gives a novel aminomethylphosphine (2). Nickel(II), palladium(II) and platinum(II) complexes of (2) have been synthesized and characterized by means of their P-31 and H-1 NMR and mass spectra and microanalytical data.