SYNTHESIS OF N-(SUBSTITUTED)ARYLAMINO GLYOXIMATO NICKEL(II) COMPLEXES


SERIN S., OKSAL B., SERINDAG O.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.22, ss.195-200, 1992 (SCI-Expanded) identifier identifier

Özet

N-Hydroxy-2-(hydroxyimino)ethanimidoyl chloride, (anti-chloroglyoxime, CGH) has been treated with 2-aminophenol and 2-amino-4-sulphoaniline respectively to give dioximes which have been isolated as nickel complexes rather than free ligands. The complexes were characterized by the elemental analysis, magnetic susceptibility measurements and H-1 nmr, infrared and atomic absorption spectroscopies.