Synthesis of a novel diazo functionalised oxime ligand and its Cu(II) and Fe(III) complexes


Guzel B., Serindag O. , Serin S.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.27, ss.301-309, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 27 Konu: 2
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00945719708000153
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayısı: ss.301-309

Özet

N-Phenyl-3-oxo-butanamide, (1), which is used in dyes and pigment synthesis, on reaction with hydroxylamine gives N-phenyl-3-hydroxyiminobutanamide (2). This compound reacts with diazonium salts to give diazo products which coordinate to copper(II) and iron(III). The intermediate obtained from the preparation of die ligand, the ligand itself and the metal complexes were characterised by magnetic susceptibility, spectroscopic techniques such as IR, H-1 NMR, UV-Vis. and microanalytical data.