X=Y-ZH Systems as potential 1,3-dipoles. Part 51: Halogen-induced inter- and intra-molecular formation of nitrones from oximes and alkenes

DÖNDAŞ H. A. , Grigg R., Hadjisoteriou M., Markandu J., Kennewell P., Thornton-Pett M.

TETRAHEDRON, cilt.57, sa.6, ss.1119-1128, 2001 (SCI İndekslerine Giren Dergi) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Konu: 6
  • Basım Tarihi: 2001
  • Dergi Adı: TETRAHEDRON
  • Sayfa Sayıları: ss.1119-1128


Grimes possessing gamma- and delta -alkenyl substituents are cyclised by N-bromo- or N-iodosuccinimide, iodine or IC1 to the corresponding cyclic nitrones or their dimeric H-bonded hydroiodide salts in good yield; facially specific cycloaddition of these nitrones, and others derived by cyclisation of delta,delta -bis(alkenyl) ketoximes or by iodine induced addition of acetaldoxime to cyclohexene, furnish isoxazolidines. (C) 2001 Elsevier Science Ltd. All rights reserved.