Synthesis, characterization and catalytic activity of chiral binaphthyl Schiff-base manganese complexes for the epoxidation of styrene

Erdem O., GÜZEL B.

INORGANICA CHIMICA ACTA, cilt.418, ss.153-156, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 418
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.ica.2014.04.004
  • Dergi Adı: INORGANICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.153-156
  • Çukurova Üniversitesi Adresli: Evet

Özet

Chiral binaphthyl Schiff base ligands were prepared by condensation of 2,2'-diamino-1,1'-binaphthalene with various salicylaldehydes. Ligands were coordinated with Mn(III) as catalysts. The catalytic efficiency of the complexes was tested on the epoxidation of styrene. The influences of the parameters such as reaction time, position of substituents with various oxidants on the epoxidation reactions were investigated. (C) 2014 Elsevier B. V. All rights reserved.