Synthesis, characterization and catalytic activity of chiral binaphthyl Schiff-base manganese complexes for the epoxidation of styrene


Erdem O. , GÜZEL B.

INORGANICA CHIMICA ACTA, cilt.418, ss.153-156, 2014 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 418
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.ica.2014.04.004
  • Dergi Adı: INORGANICA CHIMICA ACTA
  • Sayfa Sayıları: ss.153-156

Özet

Chiral binaphthyl Schiff base ligands were prepared by condensation of 2,2'-diamino-1,1'-binaphthalene with various salicylaldehydes. Ligands were coordinated with Mn(III) as catalysts. The catalytic efficiency of the complexes was tested on the epoxidation of styrene. The influences of the parameters such as reaction time, position of substituents with various oxidants on the epoxidation reactions were investigated. (C) 2014 Elsevier B. V. All rights reserved.