Experimental and theoretical investigation of 3-amino-1,2,4-triazole-5-thiol as a corrosion inhibitor for carbon steel in HCl medium
CORROSION SCIENCE, cilt.53, sa.12, ss.4265-4272, 2011 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 53 Sayı: 12
- Basım Tarihi: 2011
- Doi Numarası: 10.1016/j.corsci.2011.08.038
- Dergi Adı: CORROSION SCIENCE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.4265-4272
- Anahtar Kelimeler: Steel, EIS, Electrochemical calculation, Acid corrosion, HYDROCHLORIC-ACID SOLUTION, SCHIFF-BASE COMPOUNDS, MILD-STEEL, TRIAZOLE DERIVATIVES, ALUMINUM-ALLOY, IMPEDANCE SPECTROSCOPY, SULFURIC-ACID, ADSORPTION, H2SO4, EFFICIENCY
- Çukurova Üniversitesi Adresli: Evet
Özet
The inhibition effect of 3-amino-1,2,4-triazole-5-thiol (3ATA5T) was investigated in 0.5 M HCl on carbon steel (CS) by electrochemical impedance spectroscopy and potentiodynamic measurements at various concentrations and temperatures. Results showed that the correlation between experimental (inhibition efficiencies. Delta G(ads), E-a) and quantum calculation parameters (dipole moment, E-HOMO, E-LUMO). The high inhibition efficiency was declined in terms of strongly adsorption of protonated inhibitor molecules on the metal surface and forming a protective film. (C) 2011 Elsevier Ltd. All rights reserved.