4d core-level resonant photoemission spectroscopy of thulium monochalcogenides around the Tm 3d threshold


Nath K., Ufuktepe Y., Kimura S., Kinoshita T., Kumigashira H., Takahashi T., ...Daha Fazla

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, cilt.88, ss.369-375, 1998 (SCI-Expanded) identifier identifier

Özet

We report the results of 4d core-level photoemission spectra for thulium monochalcogenides, TmX (X = S, Se, Te) around the 3d-4f absorption edge. The resonance effect for Tm 4d emission occurs through partial decay channels of the 3d-4f excited states. The lifetime-broadening phenomenon, which depends strongly on the binding energy, is also employed here for elucidation of 4d photoelectron spectral features. The behavior of a particular decay channel, referred to as 3d-4d4f, followed by preferential excited states was studied extensively. (C) 1998 Elsevier Science B.V.