A novel catalyst system for the synthesis of N,N '-Methylenebisacrylamide from acrylamide


Avsar A., Gokbulut Y., AY B. , SERİN S.

DESIGNED MONOMERS AND POLYMERS, vol.20, pp.434-440, 2017 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 20
  • Publication Date: 2017
  • Doi Number: 10.1080/15685551.2017.1332138
  • Title of Journal : DESIGNED MONOMERS AND POLYMERS
  • Page Numbers: pp.434-440

Abstract

N, N'-Methylenebisacrylamide (MBAA), which is an important raw material in a widely industrial area, was synthesized using convenient catalysts. The synthesized monomer was fully characterized by the elemental analysis, fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), 1H-NMR, 13C-NMR, GC/MS, and high performance liquid chromatography (HPLC) analysis. Six different homogeneous and heterogeneous catalysts were used to obtain maximum monomer yield. The MBAA was obtained with 95% yield by using Cu(II) catalyst containing carboxylate groups ligands.