A novel catalyst system for the synthesis of N,N '-Methylenebisacrylamide from acrylamide

Avsar A., Gokbulut Y., AY B., SERİN S.

DESIGNED MONOMERS AND POLYMERS, cilt.20, ss.434-440, 2017 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 20
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1080/15685551.2017.1332138
  • Dergi Adı: DESIGNED MONOMERS AND POLYMERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.434-440
  • Anahtar Kelimeler: N,N '-Methylenebisacrylamide, catalyst, monomer synthesis, Cu(II) complex, SUPERABSORBENT POLYMER, HYDROGELS
  • Çukurova Üniversitesi Adresli: Evet

Özet

N, N'-Methylenebisacrylamide (MBAA), which is an important raw material in a widely industrial area, was synthesized using convenient catalysts. The synthesized monomer was fully characterized by the elemental analysis, fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), 1H-NMR, 13C-NMR, GC/MS, and high performance liquid chromatography (HPLC) analysis. Six different homogeneous and heterogeneous catalysts were used to obtain maximum monomer yield. The MBAA was obtained with 95% yield by using Cu(II) catalyst containing carboxylate groups ligands.