Phenolic Profiling of Merlot Wines from Albania: Influence of Geographical Origin and Vintage Assessed by LC-DAD-ESI-MS/MS


Topi D., Kelebek H., Shehi G., GÜÇLÜ G., SELLİ S.

Analytica, cilt.6, sa.3, 2025 (ESCI, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 6 Sayı: 3
  • Basım Tarihi: 2025
  • Doi Numarası: 10.3390/analytica6030032
  • Dergi Adı: Analytica
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus, Philosopher's Index
  • Anahtar Kelimeler: Albania, catechins, epicatechins, flavonoids, Mediterranean region, Merlot wine, phenolics, stilbenes
  • Çukurova Üniversitesi Adresli: Evet

Özet

Merlot red wines rank among the most distinguished varietals globally. This study aimed to characterize the phenolic compound profiles of Merlot wines and assess the influence of geographical origin and vintage on samples from two Albanian wine regions. Using liquid chromatography coupled with tandem mass spectrometry, a total of 31 phenolic compounds were identified and quantified. These were classified into hydroxybenzoic acids and flavan-3-ols (13 compounds), phenolic acids (9), flavonols (5), and stilbenoids (4). The total phenolic content ranged from 294 mg L−1 in wines from the Mati–Mirdita region to 480 mg L−1 in those from the Durrës–Kavaja region, demonstrating significant regional variation. Notably, the hydroxybenzoic acids and flavan-3-ols exhibited the most pronounced differences, with gallic acid concentrations varying from 123 mg L−1 (Mati–Mirdita) to 170 mg L−1 (Durrës–Kavaja). Both regions’ wines were rich in catechin, epicatechin, procyanidin derivatives, trans-caftaric acid, and ethyl gallate. However, procyanidins were found in higher concentrations in the Mati–Mirdita wines, while other phenolics were more abundant in Durrës–Kavaja samples. These findings underscore the influence of geographical and climatic factors on phenolic composition, offering a robust chemical fingerprinting approach for assessing wine authenticity and quality.