Effect of Alkaline Types on the Production of Calcium Carbonate Particles from Gypsum Waste for Fixation of CO2 by Mineral Carbonation

ALTINER M.

INTERNATIONAL JOURNAL OF COAL PREPARATION AND UTILIZATION, vol.39, no.3, pp.113-131, 2019 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 39 Issue: 3
  • Publication Date: 2019
  • Doi Number: 10.1080/19392699.2018.1452739
  • Journal Name: INTERNATIONAL JOURNAL OF COAL PREPARATION AND UTILIZATION
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.113-131
  • Keywords: Desulfurization gypsum (DG), Precipitated calcium carbonate (PCC), Phase transformation, Mineral Carbonation, CO2 sequestration, RED GYPSUM, SEQUESTRATION, PHOSPHOGYPSUM
  • Çukurova University Affiliated: Yes

Abstract

Industrial by-products have been used as an alternative raw material for the long-term storage of CO2 as a mineral carbonate with various polymorphs and properties. For example; desulfurization gypsum (DG) obtained from a power station has great potential due to its high CaO content. This study used a mineral carbonation process to produce CaCO3 particles (PCC) from DG wastes for fixation of CO2 The effects of solid-to-liquid ratio (1:13, 1:9, and 1:7) and hydroxide sources (NaOH, NH4OH) on properties of PCC were determined using XRD, SEM, FTIR, AAS, and wet chemical analyses. Calcite crystals were produced in all cases with the use of NaOH, whereas calcite crystals along with spherical vaterite crystals were observed in the presence of NH4+. This study suggested a good option due to not only fixation of CO2 but also production of PCC with a high purity.