Electrocatalytic Oxidation of Methanol on Pt/NiZn Electrode in Alkaline Medium


Telli E., Solmaz R., KARDAŞ G.

RUSSIAN JOURNAL OF ELECTROCHEMISTRY, cilt.47, ss.811-818, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 47 Konu: 7
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1134/s1023193511070135
  • Dergi Adı: RUSSIAN JOURNAL OF ELECTROCHEMISTRY
  • Sayfa Sayısı: ss.811-818

Özet

In this study, a platinum electrode was coated with NiZn layer (Pt/NiZn) in a nickel-zinc bath by electrodeposition for use as anode material for methanol electrooxidation in alkaline solution. The electrode prepared was etched in a concentrated alkaline solution (30% NaOH) to produce a porous and electrocatalytic surface suitable for use in the methanol electrooxidation (Pt/NiZn). The surface morphologies and compositions of coating before and after alkaline leaching were determined by energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. The effect of NiZn coated platinum electrode for methanol electrooxidation was investigated in 1 M NaOH solution by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques. Methanol electrooxidation on Pt/NiZn electrode was studied at various temperatures and potential scan rates. The results showed that Pt/NiZn electrode behaved as an efficient catalyst for the electrooxidation of methanol in alkaline medium.