Synthesis and application of phenylcarbamodithioate compound for steel protection


TANSUĞ G. , KICIR N., DEMİRKOL O. , Giray E. S. , TÜKEN T.

JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, cilt.30, ss.1984-2000, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 30 Konu: 18
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1080/01694243.2016.1171570
  • Dergi Adı: JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
  • Sayfa Sayıları: ss.1984-2000

Özet

Phenyldithiocarbamate compound has been synthesized and studied as corrosion inhibitor for steel. Dithiocarbamate (DTC) compounds with linear alkyl groups are good inhibitors, but their stability is quite low in acidic solutions. It should be noted that long-term stability is important for practical applications, in order to avoid excess use of chemicals. So, we have synthesized phenyl substituted DTC which offers strong inhibition efficiency and extra stability. This new inhibitor is chemically adsorbed on steel through its DTC group, while the aromatic ring provides extra stability and long-term efficiency. For the assessment of corrosion kinetics, we have utilized potentiodynamic and ac impedance studies; also solution assay analysis was realized with atomic absorption spectroscopy. It was revealed that inhibitor exhibits remarkably high efficiency, even under elevated temperature conditions. At 55 degrees C temperature conditions, i(corr) value decreased from 5050 to 154 mu A cm(-2), with the addition of 500 ppm inhibitor. The long-term stability of inhibitor was also tested and 85.93% efficiency was obtained after three days of exposure period for 500 ppm concentration.