Synthesis, characterization, electrical conductivity and luminescence properties of two copper(II) complexes with tridentate N2O chelating ligands containing imine bond


Gonul I., AY B. , KARACA S. , ŞAHİN O., SERİN S.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1156, ss.465-472, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 1156
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1016/j.molstruc.2017.12.020
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.465-472

Özet

In the present study, we describe the synthesis and characterization of two tridentate N2O donor ligands, namely, (E)-2-(((2-(diethylamino)ethyl)imino)methyl)-6-methoxyphenol (HL1) and (E)-2-(((2-(diethylamino)ethyl)imino)methyl)-6-ethoxyphenol (HL2), and their copper(II) complexes, [Cu(L-1)(CH3COO)] (1), [Cu(L-2)(CH3COO)] (2). They have been synthesized under conventional methods and characterized by elemental analysis, FTIR, H-1 and C-13 NMR, ICP-OES, TGA and GC/MS analysis. For the morphological analysis field emission scanning electron microscopy (FESEM) was used. The geometry of the copper(II) complexes was determined by single crystal X-ray diffraction analysis. The copper(II) ions are in distorted square-pyramidal coordination environments. Complexes crystallize in monoclinic space group, P2(1)/c. The electrical conductivity and luminescence properties of 1-2 have been investigated. (C) 2017 Elsevier B.V. All rights reserved.