Synthesis of biomass-based BiOI@Hydrochar heterogeneous catalyst and investigation of its activity in sonocatalytic process


Comak G., Bayram G., Görmez Ö., ÇAĞLAYAN U., Gözmen B.

Desalination and Water Treatment, cilt.320, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 320
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1016/j.dwt.2024.100625
  • Dergi Adı: Desalination and Water Treatment
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, CAB Abstracts, Environment Index, Geobase, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Advanced oxidation processes, Hydrochar, Persulfate activation, Sonocatalyst, Textile industry effluents
  • Çukurova Üniversitesi Adresli: Evet

Özet

Innovative studies in recent years to remove pollutants discharged into water resources through various means are critically important for protecting existing water resources. An important part of these studies is heterogeneous catalysis-based AOPs, where new generation composite materials are used and high organic pollutant degradation has been achieved. This study used the solvothermal approach to produce a BiOI@BH sonocatalyst doped with hydrochar (BH). A variety of analysis techniques, including XRD, FESEM, EDS, FTIR, DRS, and BET surface analysis, were used to assess changes in the physico-chemical properties of the BiOI@BH structure in comparison to BiOI. Both the adsorption and sonocatalytic degradation processes for the methylene blue aqueous solution were found to be more successful with the BiOI@BH structure. The following order of oxidative species activity was observed in sonocatalytic degradation: •OH > h+ > O2•–. Recovery studies showed that the decrease in the efficiency of the catalyst after 5 cycles in MB degradation was 10 %. It was determined that the MB degradation efficiency increased significantly with the use of persulfate oxidant at pH> 5. Finally, MB solution (20 mg L−1) was degraded by 99 % in the presence of 5 mM persulfate and 0.5 g L−1 BiOI@BH at 90 min