Synthesis of some platinum(II) diphosphine complexes of the type [PtX(2)(P-P)] (X(2)=CO3; X=CH3COO, CF3COO, NCO)

Serindag O.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, vol.27, no.1, pp.69-76, 1997 (SCI-Expanded) identifier identifier


Treatment of aminobis(methylphosphine) complexes of platinum(II) with silver(I) salts in dichloromethane gives corresponding platinum(II) complexes of the type [PtX(2)(P-P)] where X(2) = CO3; X = CH3COO, CF3COO, NCO; P-P = (Cy(2)PCH(2))(2)NMe, dcpam; (Ph(2)PCH(2))(2)NMe, dppam). The complexes have been characterised by using spectroscopic techniques such as P-31-{H-1} and H-1 NMR, IR, and mass spectrometry.