Synthesis of some platinum(II) diphosphine complexes of the type [PtX(2)(P-P)] (X(2)=CO3; X=CH3COO, CF3COO, NCO)

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Atıf İçin Kopyala

Serindag O.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.27, sa.1, ss.69-76, 1997 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 27 Sayı: 1
• Basım Tarihi: 1997
• Doi Numarası: 10.1080/00945719708000183
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.69-76
• Çukurova Üniversitesi Adresli: Evet

Özet

Treatment of aminobis(methylphosphine) complexes of platinum(II) with silver(I) salts in dichloromethane gives corresponding platinum(II) complexes of the type [PtX(2)(P-P)] where X(2) = CO3; X = CH3COO, CF3COO, NCO; P-P = (Cy(2)PCH(2))(2)NMe, dcpam; (Ph(2)PCH(2))(2)NMe, dppam). The complexes have been characterised by using spectroscopic techniques such as P-31-{H-1} and H-1 NMR, IR, and mass spectrometry.