Synthesis of some platinum(II) diphosphine complexes of the type [PtX(2)(P-P)] (X(2)=CO3; X=CH3COO, CF3COO, NCO)


Serindag O.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.27, ss.69-76, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 27 Konu: 1
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00945719708000183
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.69-76

Özet

Treatment of aminobis(methylphosphine) complexes of platinum(II) with silver(I) salts in dichloromethane gives corresponding platinum(II) complexes of the type [PtX(2)(P-P)] where X(2) = CO3; X = CH3COO, CF3COO, NCO; P-P = (Cy(2)PCH(2))(2)NMe, dcpam; (Ph(2)PCH(2))(2)NMe, dppam). The complexes have been characterised by using spectroscopic techniques such as P-31-{H-1} and H-1 NMR, IR, and mass spectrometry.