Study of using Dolomite as Starting Material Resource to Produce Magnesium Oxychloride Cement


Creative Commons License

ALTINER M., YILDIRIM M.

JOURNAL OF ADVANCED CONCRETE TECHNOLOGY, cilt.15, sa.6, ss.269-277, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 15 Sayı: 6
  • Basım Tarihi: 2017
  • Doi Numarası: 10.3151/jact.15.269
  • Dergi Adı: JOURNAL OF ADVANCED CONCRETE TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.269-277
  • Çukurova Üniversitesi Adresli: Evet

Özet

In this paper, the starting materials necessary for producing magnesium oxychloride cement (MOC) were produced from dolomite ore using leaching-carbonation-evaporation-pyrohydrolysis processes. The influences of the molar ratio of MgO/MgCl2 (M-x) and H2O/MgCl2 (H-y) on the properties of the MOC (cured for 7 days) were determined using physico-mechanical methods. SEM and XRD analyses were conducted to determine the change of phase and microstructure of the selected 7-day MOC depending on the production conduction. The experimental results show that the best mix proportion of 7-day MOC was found to be M6.06H14 and its thermal conductivity, flexural strength, and compressive strength values were found to be 1.202 W/mK, 4.22 MPa, and 87.7 MPa, respectively. The water resistance of the MOC was improved by a small amount of H3PO4 (4% of MgO by weight). Consequently, if MOC is produced from dolomite, high-purity synthetic aragonite and CO2 would be obtained as byproducts, which are strongly demanded.