Synthesis, characterization, and thermal decomposition of fluorinated salicylaldehyde Schiff base derivatives (salen) and their complexes with copper(II)

Avsar, Goektuerk; Altinel, Hueseyin; Yilmaz, Mustafa; GÜZEL, BİLGEHAN

doi:10.1007/s10973-009-0453-1

Synthesis, characterization, and thermal decomposition of fluorinated salicylaldehyde Schiff base derivatives (salen) and their complexes with copper(II)

Atıf İçin Kopyala

Avsar G., Altinel H., Yilmaz M. K., GÜZEL B.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, cilt.101, sa.1, ss.199-203, 2010 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 101 Sayı: 1
Basım Tarihi: 2010
Doi Numarası: 10.1007/s10973-009-0453-1
Dergi Adı: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.199-203
Çukurova Üniversitesi Adresli: Evet

Özet

Trifluoromethoxy functionalized copper(II) Schiff base complexes N,N'-bis(5-trifluoromethoxysalicylaldehyde)cyclohexanediiminatodiaquacopper(II) and N,N'-bis(5-trifluoromethoxysalicylaldehyde)phenylenediiminatocopper(II) were synthesized and characterized. Thermal decompositions of the synthesized complexes were studied by thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. Three similar decomposition steps occurred for the two copper complexes. Mass losses and evolved gasses were characterized by TG/DTA-MS. Kinetic parameters were calculated and the results showed that the values obtained are comparable.