Synthesis, characterization, and thermal decomposition of fluorinated salicylaldehyde Schiff base derivatives (salen) and their complexes with copper(II)


Avsar G., Altinel H., Yilmaz M. K. , GÜZEL B.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, cilt.101, ss.199-203, 2010 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 101 Konu: 1
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1007/s10973-009-0453-1
  • Dergi Adı: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Sayfa Sayısı: ss.199-203

Özet

Trifluoromethoxy functionalized copper(II) Schiff base complexes N,N'-bis(5-trifluoromethoxysalicylaldehyde)cyclohexanediiminatodiaquacopper(II) and N,N'-bis(5-trifluoromethoxysalicylaldehyde)phenylenediiminatocopper(II) were synthesized and characterized. Thermal decompositions of the synthesized complexes were studied by thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. Three similar decomposition steps occurred for the two copper complexes. Mass losses and evolved gasses were characterized by TG/DTA-MS. Kinetic parameters were calculated and the results showed that the values obtained are comparable.