Effect of several ionic liquids on the synthesis of 1,3-diphenyl-3-(phenylamino)propan-1-one in supercritical carbondioxide

VAYISOĞLU GİRAY E. S., Chiappe C., Tunali Z., Rajamani S.

RSC ADVANCES, vol.1, no.5, pp.761-764, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1 Issue: 5
  • Publication Date: 2011
  • Doi Number: 10.1039/c1ra00031d
  • Journal Name: RSC ADVANCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.761-764
  • Çukurova University Affiliated: Yes

Abstract

We found that in a scCO(2)-ionic liquid hybrid reaction system, Mannich reaction of benzaldehyde, aniline and acetophenone can be remarkably accelerated and the yield of Mannich base 1,3-diphenyl-3-(phenylamino)propan-1-one was significantly high. This system would be available for the green reactions with good performance.