The effect of metalation processes on polymer morphology and conductivity properties

Saribiyik O. Y., Gonul I., AY B., KARACA S.

POLYMERS & POLYMER COMPOSITES, vol.29, no.9_SUPPL, 2021 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 29 Issue: 9_SUPPL
  • Publication Date: 2021
  • Doi Number: 10.1177/09673911211048287
  • Journal Name: POLYMERS & POLYMER COMPOSITES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Keywords: Coordination polymers, electrical conductivity, luminescence measurements, BASE LIGAND SYNTHESIS, PI-PI STACKING, SCHIFF-BASE, COORDINATION POLYMERS, CRYSTAL-STRUCTURE, ELECTRICAL-CONDUCTIVITY, STRUCTURAL-CHARACTERIZATION, COPPER(II) COMPLEXES, LUMINESCENCE, EMISSION
  • Çukurova University Affiliated: Yes

Abstract

In this work, an insoluble three dimensional (3D) porous polymeric structure and their metal complexes were synthesised by the condensation reactions of meto(m)-phenylenediamine, para(p)-phenylenediamine and glutaraldehyde. The morphological and spectral features of the porous polymeric structures were determined using different analytical and spectroscopic methods, including field emission scanning electron microscopy, four-point probe electrical conductivity, photoluminescence spectroscopy, Fourier-transform infrared spectroscopy, surface area Brunauer-Emmett-Teller and magnetic and thermal behaviours. According to the obtained data, the shape, size and photoluminescence properties of the compounds, especially the conductivity, were clearly changed after the metalation processes.