Mild Conditions for Oxidation/Epoxidation of Styrene

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Kazanci A., Saribiyik O. Y., Serin S.

DESIGNED MONOMERS AND POLYMERS, cilt.14, sa.6, ss.559-570, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 6
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1163/156855511x598641
  • Dergi Adı: DESIGNED MONOMERS AND POLYMERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.559-570
  • Çukurova Üniversitesi Adresli: Evet

Özet

In this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p-phenylene-and o-phenylenediamine. Additionally, catalytic activity of polymeric Schiff base metal on oxidation/epoxidation of styrene complexes were investigated. The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, H-1- and C-13-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry. (C) Koninklijke Brill NV, Leiden, 2011