Synthesis and complex formation of di[4-(11-chloro-3,6,9-trioxaundecyloxy)-phenylamino]glyoxime

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Atıf İçin Kopyala

Kurtoglu M., Serin S.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.31, sa.7, ss.1229-1237, 2001 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 31 Sayı: 7
• Basım Tarihi: 2001
• Doi Numarası: 10.1081/sim-100106860
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1229-1237
• Çukurova Üniversitesi Adresli: Hayır

Özet

Di[4-(11-chloro-3,6,9-trioxaundecyloxy)phenylamino]glyoxime (LH2) has been prepared from 1-amino-4-(11-chloro-3,6,9-trioxaundecyloxy)benzene, anti-dichloroglyoxime, and sodium carbonate in ethanol. Nickel(II), copper(II) and cobalt(II) complexes of the ligand were synthesized. The Cu(II), Ni(II) and Co(II) complexes of the vic-dioxime ligand LH2 have a metal/ligand ratio of 1:2 and the ligand coordinates only through the N, N atoms, as do most vicinal dioximes. The structures of the ligand and its complexes were investigated by elementel analyses, magnetic susceptibility measurements, H-1 NMR, IR and U.V.-Visible spectroscopy.