Syntheses and characterization of 4-(11-chloro-3,6,9-trioxaundecyloxy)phenylamino-glyoxime and its complexes with copper(II), nickel(II), and cobalt(II)


Kurtoglu M., Serin S.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.32, ss.629-637, 2002 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 32 Konu: 3
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1081/sim-120003801
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayısı: ss.629-637

Özet

A novel vic-dioxime ligand containing ethyleneoxy groups, 4-(11-chloro-3,6,9-trioxaundecyloxy)phenylaminoglyoxime (LH2) has been prepared from 1-amino-4-(11-chloro-3,6,9-trioxaundecyloxy)benzene and monochloro, anti-glyoxime. Its complexes, Ni(LH)(2), Cu(LH)(2) and Co(LH)(2), have been synthesized. The analytical data show that the metal to ligand ratio in the complexes is 1:2. The complexes are formed by coordination of N,N atoms of the ligand. The structures of the oxime ligand (LH2) and its complexes were elucidated by H-1 NMR, IR, UV.-Visible and elemental analyses techniques.