Thermoluminescence properties and trap parameters of undoped K₃Gd(BO₂)₆ phosphor


Altowyan A. S., Cin E. A., Bulcar K., Coban M., Kaynar U., Gok C., ...Daha Fazla

Materials Research Bulletin, cilt.202, 2026 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 202
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.materresbull.2026.114190
  • Dergi Adı: Materials Research Bulletin
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Anahtar Kelimeler: Anti-fading behavior, Mixed traps, Trap structure, Undoped K₃Gd(BO₂)₆
  • Çukurova Üniversitesi Adresli: Evet

Özet

Undoped K₃Gd(BO₂)₆ powders were synthesized by microwave-assisted sol–gel combustion and confirmed as a single-phase borate by X-ray diffraction. The material is investigated as a potential thermoluminescent (TL) dosimeter for radiation detection. A 410 nm detection window produced intense, well-resolved glow peaks dominated by intrinsic defect- and Gd-related recombination. The TL glow curve exhibits a dominant dosimetric peak at ∼268 °C, preserved after preheating at 190 °C for 9 s. The material shows a stable and reproducible TL response over the ∼7–500 Gy dose range, with sublinear behavior and a minimum detectable dose of ∼0.2 Gy, indicating suitability for medium- to high-dose dosimetry. Kinetic analysis based on CGCD, supported by Tₘ–Tstop and initial rise methods, reveals a dominant trap depth of ∼2.2 eV. These findings demonstrate that undoped K₃Gd(BO₂)₆ is a promising dopant-free TL phosphor for radiation dosimetry applications.