Synthesis and Characterization of Aminophosphines, Bis(amino) phosphine Derivatives, and Their Molybdenum(0) Complexes

Sarioz, Ozlem; Serindag, OSMAN; Abdullah, Meysun

doi:10.1080/10426500802341275

Synthesis and Characterization of Aminophosphines, Bis(amino) phosphine Derivatives, and Their Molybdenum(0) Complexes

Atıf İçin Kopyala

Sarioz O., Serindag O., Abdullah M. I.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.184, sa.7, ss.1785-1795, 2009 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 184 Sayı: 7
Basım Tarihi: 2009
Doi Numarası: 10.1080/10426500802341275
Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1785-1795
Çukurova Üniversitesi Adresli: Evet

Özet

Functionalized bis(amino)phosphines of the type PhP(NHR)(2) (1a-c) and aminophosphines of the type Ph(2)PNHR (2a-c) have been synthesized by treating PhPCl(2) or Ph(2)PCl with corresponding primary amines of H(2)N-R where R = -CH(2)SO(3)H, -C(6)H(4)SO(3)H, and benzo-15-crown-5. The molybdenum(0) complex of the aminophosphine (3) has been obtained by reacting cis-[Mo(CO)(4)(bipy)] with aminophosphine (2c). The synthesized aminophosphines, bis(amino) phosphines, and the molybdenum(0) complex have been characterized by IR, (1)H NMR, (31)P NMR, and MS spectroscopic techniques and by elemental analysis.