Synthesis and Characterization of Aminophosphines, Bis(amino) phosphine Derivatives, and Their Molybdenum(0) Complexes


Sarioz O., Serindag O. , Abdullah M. I.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.184, ss.1785-1795, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 184 Konu: 7
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1080/10426500802341275
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.1785-1795

Özet

Functionalized bis(amino)phosphines of the type PhP(NHR)(2) (1a-c) and aminophosphines of the type Ph(2)PNHR (2a-c) have been synthesized by treating PhPCl(2) or Ph(2)PCl with corresponding primary amines of H(2)N-R where R = -CH(2)SO(3)H, -C(6)H(4)SO(3)H, and benzo-15-crown-5. The molybdenum(0) complex of the aminophosphine (3) has been obtained by reacting cis-[Mo(CO)(4)(bipy)] with aminophosphine (2c). The synthesized aminophosphines, bis(amino) phosphines, and the molybdenum(0) complex have been characterized by IR, (1)H NMR, (31)P NMR, and MS spectroscopic techniques and by elemental analysis.