Supercritical carbon dioxide-soluble fluorus vic-dioxime Ligands and their Ni-II complexes: Synthesis, characterization and solubility properties


GÜZEL B., Avsar G., CINKIR H. F.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.37, no.10, pp.801-804, 2007 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 37 Issue: 10
  • Publication Date: 2007
  • Doi Number: 10.1080/15533170701740982
  • Journal Name: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.801-804

Abstract

New supercritical carbon dioxide s oluble ligands, N,N'-bis(4-trifluoromethyl phenylamino)glyoxime, N,N'-bis(3-triftuoromethylphenylamino)glyoxime, NN'-bis(3,5-ditrifluoromethyl phenylamino)glyoxime and their Ni-II complexes have been prepared and characterized by spectroscopic methods and elemental analysis. The solubility of the synthesized ligands and their Ni-II complexes were measured at 343.15 K and 172.4 bar in supercritical carbon dioxide.