CORRELATION OF HEATS OF MIXING DATA BY THE NRTL AND UNIQUAC MODELS .1. ESTIMATION OF THE MODEL PARAMETERS


DEMIREL Y., GECEGORMEZ H., PAKSOY H.

THERMOCHIMICA ACTA, cilt.194, ss.329-341, 1992 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 194
  • Basım Tarihi: 1992
  • Doi Numarası: 10.1016/0040-6031(92)80031-q
  • Dergi Adı: THERMOCHIMICA ACTA
  • Sayfa Sayıları: ss.329-341

Özet

Using data for heats of mixing h(E), temperature dependent parameters of the NRTL and UNIQUAC models have been estimated for 57 systems of binary mixtures. In order to test the models thoroughly, systems of various types, including associating and partially miscible systems, that have data for h(E) at more than one different isotherm are considered. Temperature dependences of the models are assumed as non-linear. This form of dependence is found to be more suitable for associating systems and for prediction of excess heat capacity C(p)E from differentiation of a correlation for h(E). No fixed values are assumed for the parameters of the models. The physical meanings and non-uniqueness of the parameters are discussed.